03 Heat and Work
Addable QuantitiesΒΆ
- mass
- volume
- U
- H
- for closed system
note that specific quanties like can not be added
WorkΒΆ
SpringΒΆ
ElectricΒΆ
Boundary WorkΒΆ
Note that temperature should be in (Kelvin)
Type | Condition(s) | \(W_b\) | |
---|---|---|---|
Isochoric | \(V = c\) | \(0\) | |
Isobaric | \(P = c\) | \(P_1(V_2 - V_1)\) | \(mP_1(\nu_2 - \nu_1)\) |
Isothermal | \(\begin{aligned} T &= c \\ PV &= mRT \\ P_1 V_1 &= P_2 V_2 \end{aligned}\) | \(P_i V_i \ \ln \vert \frac{V_2}{V_1} \vert \\ P_i V_i \ \ln \vert \frac{P_1}{P_2} \vert\) | \(mRT \ \ln \vert \frac{V_2}{V_1} \vert\) \(mRT \ \ln \vert \frac{P_1}{P_2} \vert\) |
Polytropic | \(\begin{aligned} P V^n &= c \\ P_1 (V_1)^n &= P_2 (V_2)^n \\ \frac{P_1}{P_2} &= \left( \frac{V_2}{V_1} \right)^n \end{aligned}\) | \(\frac{P_2 V_2 - P_1 V_1}{1-n}\) | \(\frac{mR(T_2 - T_1)}{1-n}\) |
Sign ConventionΒΆ
Quantity | Sign |
---|---|
\(Q_\text{in}\) | + |
\(Q_\text{out}\) | - |
\(W_\text{in}\) | - |
\(W_\text{out}\) | + |
expansion | + |
compression | - |